Isobaric low-pressure vapor-liquid equilibrium data of the system monochloroacetic acid+dichloroacetic acid+diethylene glycol dipentyl ether and the constituent binary systems

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Jongmans, M.T.G. and Londono, A. and Schuur, B. and Haan de, A.B. (2012) Isobaric low-pressure vapor-liquid equilibrium data of the system monochloroacetic acid+dichloroacetic acid+diethylene glycol dipentyl ether and the constituent binary systems. Fluid phase equilibria, 334 . 15 - 21. ISSN 0378-3812

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Abstract:In this study, binary and ternary VLE data have been determined at 5, 7.5, and 10 kPa for the system monochloracetic acid (MCA) + dichloroacetic acid (DCA) + diethylene glycol dipentyl ether (DGDP). The extractant DGDP enhances the relative volatility of the MCA/DCA system from 1.2 without extractant up to 4. The non-ideal behavior in the liquid and vapor phase was reasonably well correlated with the NRTL and Hayden–O’Connell (HOC) model, respectively. The binary and ternary VLE data were correlated separately to obtain a better description of both datasets
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Science and Technology (TNW)
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Link to this item:http://purl.utwente.nl/publications/81926
Official URL:http://dx.doi.org/10.1016/j.fluid.2012.07.027
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