Self-trapped vibrational states in synthetic β-sheet helices


Schwartz, Erik and Bodis, Pavol and Koepf, Matthieu and Cornelissen, Jeroen J.L.M. and Rowan, Alan E. and Woutersen, Sander and Nolte, Roeland J.M. (2009) Self-trapped vibrational states in synthetic β-sheet helices. Chemical Communications (31). pp. 4675-4677. ISSN 1359-7345

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Abstract:Femtosecond vibrational pump–probespectroscopy on β-helical polyisocyanopeptides reveals vibrational self-trapping in the well-defined hydrogen-bonded side groups that is absent when non-hydrogen bonded monomers are mixed in.

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