Synthesis, Characterization, and Surface Initiated Polymerization of Carbazole Functionalized Isocyanides

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Schwartz, Erik and Lim, Eunhee and Gowda, Chandrakala M. and Liscio, Andrea and Fenwick, Oliver and Tu, Guoli and Palermo, Vincenzo and Gelder, Rene de and Cornelissen, Jeroen J.L.M. and Eck, Ernst R.H. van and Kentgens, Arno P.M. and Cacialli, Franco and Nolte, Roeland J.M. and Samori, Paolo and Huck, Wilhelm T.S. and Rowan, Alan E. (2010) Synthesis, Characterization, and Surface Initiated Polymerization of Carbazole Functionalized Isocyanides. Chemistry of Materials, 22 (8). pp. 2597-2607. ISSN 0897-4756

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Abstract:We describe the design and synthesis of carbazole functionalized isocyanides and the detailed investigation of their properties. Characterization by solid state NMR, CD, and IR spectroscopic techniques reveals that the polymer has a well-defined helical architecture. Surface-initiated polymerization of the isocyanide monomers onto various surfaces was carried out to give polymer brushes up to 150 nm thick. Insights into the electronic properties of the materials were obtained by Kelvin probe force microscopy (KPFM) and electroabsorption studies
Item Type:Article
Copyright:© 2010 American Chemical Society
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Science and Technology (TNW)
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Link to this item:http://purl.utwente.nl/publications/77549
Official URL:http://dx.doi.org/10.1021/cm903664g
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Metis ID: 273737