Control over Rectification in Supramolecular Tunneling Junctions


Wimbush, Kim S. and Reus, William F. and Wiel, Wilfred G. van der and Reinhoudt, David N. and Whitesides, George M. and Nijhuis, Christian A. and Velders, Aldrik H. (2010) Control over Rectification in Supramolecular Tunneling Junctions. Gesellschaft Deutscher Chemiker, 49 (52). pp. 10176-10180. ISSN 1521-3773

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Abstract:In complete control: The magnitude of current rectification in well-defined supramolecular tunneling junctions can be controlled by changing the terminal functionality (red spheres) of dendrimers (gray spheres) immobilized on a supramolecular platform (see picture). Junctions containing biferrocene and ferrocene end groups showed larger rectification ratios than junctions containing adamantyl end groups.

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Copyright:© 2010 Wiley
Electrical Engineering, Mathematics and Computer Science (EEMCS)
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