Electrochemistry of potential bioreductive alkylating quinones : Part 2. Electrochemical properties of 2,5-bis(1-aziridinyl)-3,6-bis(ethoxycarbonylamino)-1,4-benzoquinone and some model compounds

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Driebergen, R.J. and Holthuis, J.J.M. and Blauw, J.S. and Postma Kelder, S.J. and Verboom, W. and Reinhoudt, D.N. and Linden, W.E. van der (1990) Electrochemistry of potential bioreductive alkylating quinones : Part 2. Electrochemical properties of 2,5-bis(1-aziridinyl)-3,6-bis(ethoxycarbonylamino)-1,4-benzoquinone and some model compounds. Analytica Chimica Acta, 234 . pp. 285-307. ISSN 0003-2670

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Abstract:The reduction mechanism of 2,5-bis(1-aziridinyl)-3,6-bis(ethoxycarbonylamino)-1,4-benzoquinone (Diaziquone, AZQ) and several model compounds of the mono- and bis(1-aziridinyl)quinone type at the dropping mercury electrode in aqueous solutions was studied. In addition, the influence of methyl substitution of the aziridinyl moiety at the 2-position on the protonation of the aziridine nitrogen was investigated. Substituent effects on quinone reduction and aziridine protonation prior to and following quinone reduction were studied qualitatively.
Item Type:Article
Copyright:© 1990 Elsevier
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Science and Technology (TNW)
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Link to this item:http://purl.utwente.nl/publications/72915
Official URL:http://dx.doi.org/10.1016/S0003-2670(00)83570-9
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