Selected Examples of High-Pressure Reactions in Glass Microreactors

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Verboom, Willem (2009) Selected Examples of High-Pressure Reactions in Glass Microreactors. Chemical Engineering & Technology, 32 (11). pp. 1695-1701. ISSN 0930-7516

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Abstract:Recent examples of high-pressure organic reactions in (flow) glass microreactors of micrometer dimensions are described. Different types of reactions such as Diels-Alder and nucleophilic aromatic substitution reactions performed in a capillary microreactor gave rate enhancements of 1.5–2.7 at 600 bar. Specifically designed flow glass microreactors, that withstand pressures of 140–690 bar, were used to study Diels-Alder and oxidation reactions. The use of supercritical fluids gives rise to considerable rate enhancements, while the use of a transparent microreactor allows to visualize phase transitions.
Item Type:Article
Copyright:© 2009 Wiley
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Science and Technology (TNW)
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Link to this item:http://purl.utwente.nl/publications/72778
Official URL:http://dx.doi.org/10.1002/ceat.200900369
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