Alkane Activation at Ambient Temperatures: Unusual Selectivities, C-C, C-H Bond Scission versus C-C Bond Coupling

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Trionfetti, Cristiano and Agiral, Anil and Gardeniers, Han J.G.E. and Lefferts, Leon and Seshan, Kulathuiyer (2008) Alkane Activation at Ambient Temperatures: Unusual Selectivities, C-C, C-H Bond Scission versus C-C Bond Coupling. ChemPhysChem, 9 (4). pp. 533-537. ISSN 1439-4235

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Abstract:Activating bonds: A cold plasma generated by dielectric barrier discharge in a microreactor converts alkanes (C1–C3) at atmospheric pressure. Large amounts of products with higher molecular weight than the starting hydrocarbons are observed showing that C-H activation at lower T favourably leads to C-C bond formation.
Item Type:Article
Copyright:© 2008 Wiley
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Science and Technology (TNW)
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Link to this item:http://purl.utwente.nl/publications/72567
Official URL:http://dx.doi.org/10.1002/cphc.200700757
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Metis ID: 246851