Self-Assembled Monolayers of a Multifunctional Organic Radical


Crivillers, Núria and Mas-Torrent, Marta and Perruchas, Sandrine and Roques, Nans and Vidal-Gancedo, José and Veciana, Jaume and Rovira, Concepció and Basabe-Desmonts, Lourdes and Ravoo, Bart Jan and Crego-Calama, Mercedes and Reinhoudt, David N. (2007) Self-Assembled Monolayers of a Multifunctional Organic Radical. Angewandte Chemie, International Edition in English, 46 (13). pp. 2215-2219. ISSN 0570-0833

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Abstract:A radical switch: Covalent and noncovalent interactions have been used to functionalize silicon oxide surfaces with polychlorotriphenylmethyl radicals, which are electroactive and can be reversibly reduced or oxidized to nonmagnetic and nonfluorescent species. Thus, the self-assembled monolayers behave as chemical switches that combine electronic absorption, fluorescence emission, and magnetic outputs.
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Copyright:© 2007 Wiley InterScience
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Metis ID: 241415