Amplification of Chirality in Hydrogen-Bonded Tetrarosette Helices


Mateos-Timoneda, Miguel A. and Crego-Calama, Mercedes and Reinhoudt, David N. (2006) Amplification of Chirality in Hydrogen-Bonded Tetrarosette Helices. Chemistry: a European Journal, 12 (9). pp. 2630-2638. ISSN 0947-6539

[img] PDF
Restricted to UT campus only
: Request a copy
Abstract:The amplification of chirality in hydrogen-bonded tetrarosette assemblies under thermodynamic equilibrium is described. The extent of the chiral amplification obtained by means of sergeants-and-soldiers experiments depends only on the structure of the assembly and it is independent of the methodology used for the formation of the tetrarosette assemblies. The difference in free energy (Δ
GoM/P) between the M- and P-diastereomeric helices is up to 40 times higher than for double rosette assemblies.
Item Type:Article
Copyright:© 2006 Wiley InterScience
Research Group:
Link to this item:
Official URL:
Export this item as:BibTeX
HTML Citation
Reference Manager


Repository Staff Only: item control page