Dynamic Materials through Metal-Directed and Solvent-Driven Self-Assembly of Cavitands

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Pirondini, Laura and Stendardo, Anna G. and Geremia, Silvano and Samori, Paolo and Rabe, Jürgen P. and Fokkens, Roel and Dalcanale, Enrico (2003) Dynamic Materials through Metal-Directed and Solvent-Driven Self-Assembly of Cavitands. Angewandte Chemie, International Edition in English, 42 (12). pp. 1384-1387. ISSN 0570-0833

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Abstract:A dual-coded dynamic material was created by the bimodal self-assembly protocol sketched in the scheme. The combination of two orthogonal and reversible interactions, namely solvophobic aggregation (SA) and metal coordination (MC), allows precise control at each step of the self-assembly cycle, leading to the formation of rodlike supramolecular architectures.
Item Type:Article
Copyright:© 2003 Wiley InterScience
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Link to this item:http://purl.utwente.nl/publications/71938
Official URL:http://dx.doi.org/10.1002/anie.200390355
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