Polymerization of ethylene oxide using yttrium isopropoxide

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Choi, Young K. and Stevels, Willem M. and Ankone, Marc J.K. and Dijkstra, Pieter J. and Kim, Sung W. and Feijen, Jan (1996) Polymerization of ethylene oxide using yttrium isopropoxide. Macromolecular Chemistry and Physics, 197 (11). pp. 3623-3629. ISSN 1022-1352

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Abstract:Well defined poly(ethylene oxide)s were prepared using yttrium isopropoxide as an initiator. End group analysis using 1H- and 13C NMR spectroscopy revealed that only polymers with isopropyl ether and hydroxyl end groups were produced. The molecular weight is controlled by the initial amount of initiator added and low polydispersity polymer (Mw/Mn ≈ 1.1) was isolated. Sequential polymerization indicated the suitability of this initiator for macromolecular engineering.
Item Type:Article
Copyright:© 1996 Wiley InterScience
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Science and Technology (TNW)
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Link to this item:http://purl.utwente.nl/publications/71255
Official URL:http://dx.doi.org/10.1002/macp.1996.021971111
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Metis ID: 105387