Novel applications of the “t-amino effect” in heterocyclic chemistry; synthesis of 1-alkylindoles

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Dijksman, W.C. and Verboom, W. and Reinhoudt, D.N. and Hale, C.G. and Harkema, S. and Hummel van, G.J. (1984) Novel applications of the “t-amino effect” in heterocyclic chemistry; synthesis of 1-alkylindoles. Tetrahedron Letters, 25 (19). pp. 2025-2028. ISSN 0040-4039

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Abstract:Thermal rearrangerment of 2-vinyl-1-(1-pyrrolidinyl)benzenes varies with the leaving group ability of substituents in the vinyl moiety; compound 3 having an OR group 9-(alkoxy-methyl)pyrrolo[1,2-a]indoles and compounds 6 (X = OAc, OTs or Cl) yield 1-alkylindoles.
Item Type:Article
Copyright:© 1984 Elsevier Science
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Science and Technology (TNW)
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Link to this item:http://purl.utwente.nl/publications/69369
Official URL:http://dx.doi.org/10.1016/S0040-4039(01)90103-0
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