13C-n.m.r. spectra of acrylophenone (1-phenylprop-2-en-1-one) and ring-substituted acrylophenones

Share/Save/Bookmark

Visser, R. and Dahmen, E.A.M.F. (1978) 13C-n.m.r. spectra of acrylophenone (1-phenylprop-2-en-1-one) and ring-substituted acrylophenones. Analytica Chimica Acta, 100 . pp. 271-277. ISSN 0003-2670

open access
[img]
Preview
PDF
419kB
Abstract:13C-n.m.r. chemical shifts of 10 acrylophenones (1-substituted phenylprop-2-en-1-ones) are reported. The additivity parameters for the substituent effect of the acryloyl group in the aromatic ring and of the benzoyl group in ethylene were calculated. Comparison of ethene chemical shifts in chalcones (1,3-diphenylpropenones) with calculated values yielded good results, showing that cross conjugation in these molecules is of little importance. Chemical shifts in acrylophenones and chalcones can therefore be calculated as linear combinations of the mutual effects of the constituent groups.
Item Type:Article
Copyright:© 1978 Elsevier Science
Link to this item:http://purl.utwente.nl/publications/68393
Official URL:http://dx.doi.org/10.1016/S0003-2670(01)93323-9
Export this item as:BibTeX
EndNote
HTML Citation
Reference Manager

 

Repository Staff Only: item control page