Pyrazoles and imidazoles as ligands. X. electron paramagnetic resonance spectra of MnII in a tetragonal environment of four pyrazoles and two anions

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Dowsing, R.D. and Nieuwenhuijse, B. and Reedijk, J. (1971) Pyrazoles and imidazoles as ligands. X. electron paramagnetic resonance spectra of MnII in a tetragonal environment of four pyrazoles and two anions. Inorganica Chimica Acta, 5 . pp. 301-304. ISSN 0020-1693

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Abstract:Electron Paramagnetic Resonance Spectra have been recorded for some compounds of the type Mn(ligand)4- (anion)2, with pyrazole and 3(5)-methyl pyrazole as the ligands, and Cl−, Br−, I−, and NO3−, as the anions.

The spectra show absorptions far from geff=2 for all compounds at both X- and Q-band frequencies. these spectra can be interpreted on the basis of a slightly distorted D4h symmetry for S=5/2, with D= 0.05–1.5 cm−1 and λ (being equal to E/D)=0.01–0.1

The different values of the parameters for the several compounds can be explained by differences in the axial ligand-field strengths.
Item Type:Article
Copyright:© 1971 Elsevier Science
Link to this item:http://purl.utwente.nl/publications/68112
Official URL:http://dx.doi.org/10.1016/S0020-1693(00)95933-4
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