Integer charge transfer at the tetrakis(dimethylamino)ethylene/Au interface


Lindell, L. and Unge, M. and Osikowicz, W. and Stafstrom, S and Salaneck, W.R. and Crispin, X. and Jong, M.P. de (2008) Integer charge transfer at the tetrakis(dimethylamino)ethylene/Au interface. Applied physics letters, 92 . p. 163302. ISSN 0003-6951

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Abstract:In organic-based electronics, interfacial properties have a profound impact on device performance. The lineup of energy levels is usually dependent on interface dipoles, which may arise from charge transfer reactions. In many applications, metal-organic junctions are prepared under ambient conditions, where direct overlap of the organic system from the metal bands is prevented due to presence of oxides and/or hydrocarbons. We present direct experimental and theoretical evidence showing that the interface energetic for such systems is governed by exchange of an integer amount of electrons.
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Copyright:© 2008 American Institute of Physics
Electrical Engineering, Mathematics and Computer Science (EEMCS)
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Metis ID: 252097