Electrode Properties of Sr-Doped LaMnO3 on Yttria-Stabilized Zirconia II: Electrode kinetics

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Heuveln van, F.H. and Bouwmeester, H.J.M. (1997) Electrode Properties of Sr-Doped LaMnO3 on Yttria-Stabilized Zirconia II: Electrode kinetics. Journal of the Electrochemical Society, 144 (1). pp. 134-140. ISSN 0013-4651

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Abstract:A series of six cathodes Sr0.15La0.85MnO3 (SLM) on yttria-stabilized zirconia with different morphology of the electrode/electrolyte interface were characterized by ac impedance and dc polarization measurements. It is found that the electrode kinetics at elevated temperature (945°C) are governed by two serial processes. An activation process can be identified to occur at high cathodic overpotential, whereas a transport process competes with charge-transfer at comparatively low overpotential. Attention is drawn to the profound change in the electrocatalytic properties of Sr0.15La0.85MnO3 upon current passage and its influence in elucidation of the interfacial kinetics.
Item Type:Article
Copyright:The Electrochemical Society
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Science and Technology (TNW)
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Link to this item:http://purl.utwente.nl/publications/61584
Official URL:http://dx.doi.org/10.1149/1.1837375
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Metis ID: 106484