Distribution of ions around a charged sphere

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Strating, P. and Wiegel, F.W. (1993) Distribution of ions around a charged sphere. Physica A: Theoretical and statistical physics, 193 (3-4). pp. 413-420. ISSN 0378-4371

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Abstract:Using a new method of calculating the effects of excluded volume, the authors evaluate the distribution of counterions around a charged sphere in thermal equilibrium. In regions of high concentration a saturation of the ion density is found, which is absent in the more conventional Gouy-Chapman model. At the same time the saturation effect of the potential (a property of the Gouy-Chapman model) is removed, giving significant corrections to the values of the potential and concentration at the surface of the sphere.
Item Type:Article
Copyright:© 1993 Elsevier Science
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Link to this item:http://purl.utwente.nl/publications/61306
Official URL:http://dx.doi.org/10.1016/0378-4371(93)90484-L
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Metis ID: 129611