Synthesis and binding properties of novel cyclodextrin dimers


Venema, Fokke and Baselier, Chantal M. and Dienst, Erik van and Ruël, Bianca H.M. and Feiters, Martinus C. and Engbersen, Johan F.J. and Reinhoudt, David N. and Nolte, Roeland J.M. (1994) Synthesis and binding properties of novel cyclodextrin dimers. Tetrahedron letters, 35 (11). pp. 1773-1776. ISSN 0040-4039

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Abstract:The synthesis of three cyclodextrin dimers from the novel building block 3-amino-3-deoxy-heptakis(6-O-tert-butyldimethylsilyl)-ß-cyclodextrin is reported. The cyclodextrins are linked with an amide bond on their secondary sides to an ethylene, octamethylene, or a metal binding bipyridyl group. Complexation studies with the substrate 6-(p-toluidino)-2-naphthalenesulfonic acid are presented and discussed.
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Copyright:© 1994 Elsevier Science
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