Optical fiber-based-o-line UV/V is spectroscopic monitoring of chemical reaction kinetics under high pressure in a capillary microreactor

Benito-Lopez, Fernando and Verboom, Willem and Kakuta, Masaya and Gardeniers, J.G.E. (Han) and Egberink, Richard J.M. and Oosterbroek, Edwin R. and Berg van den, Albert and Reinhoudt, David N. (2005) Optical fiber-based-o-line UV/V is spectroscopic monitoring of chemical reaction kinetics under high pressure in a capillary microreactor. Chemical Communications, 2005 (22). pp. 2857-2859. ISSN 1359-7345

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Abstract:	With a miniaturized (3 µL volume) fiber-optics based system for on-line measurement by UV/Vis spectroscopy, the reaction rate constants (at different pressures) and the activation volumes (V) were determinined for a nucleophilic aromatic substitution and an aza Diels–Alder reaction in a capillary microreactor.
Item Type:	Article
Copyright:	© 2005 Royal Society of Chemistry
Faculty:	Science and Technology (TNW) Electrical Engineering, Mathematics and Computer Science (EEMCS)
Research Group:	Molecular Nanofabrication (MNF) Mesoscale Chemical Systems (MCS) Biomedical and Environmental Sensor systems (BIOS)
Link to this item:	http://purl.utwente.nl/publications/53001
Official URL:	http://dx.doi.org/10.1039/b500429b
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