Controlling the amplification of chirality in hydrogen-bonded assemblies


Mateos-Timoneda, Miguel A. and Crego-Calama, Mercedes and Reinhoudt, David N. (2005) Controlling the amplification of chirality in hydrogen-bonded assemblies. Supramolecular Chemistry, 17 (1-2). pp. 67-79. ISSN 1061-0278

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Abstract:The amplification of chirality (a high enantiomeric or diastereomeric excess induced by a small initial amount of chiral bias) on hydrogen-bonded assemblies has been studied using “sergeants-and-soldiers” experiments under thermodynamically controlled conditions. Here it is shown that different substitutions and structural variations in the building blocks that form these self-assembled systems can be used to control the extent of the chiral amplification.
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Copyright:© 2005 Taylor & Francis
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Metis ID: 224849