Controlling the amplification of chirality in hydrogen-bonded assemblies

Share/Save/Bookmark

Mateos-Timoneda, Miguel A. and Crego-Calama, Mercedes and Reinhoudt, David N. (2005) Controlling the amplification of chirality in hydrogen-bonded assemblies. Supramolecular Chemistry, 17 (1-2). pp. 67-79. ISSN 1061-0278

[img]PDF
Restricted to UT campus only
: Request a copy
515Kb
Abstract:The amplification of chirality (a high enantiomeric or diastereomeric excess induced by a small initial amount of chiral bias) on hydrogen-bonded assemblies has been studied using “sergeants-and-soldiers” experiments under thermodynamically controlled conditions. Here it is shown that different substitutions and structural variations in the building blocks that form these self-assembled systems can be used to control the extent of the chiral amplification.
Item Type:Article
Copyright:© 2005 Taylor & Francis
Research Group:
Link to this item:http://purl.utwente.nl/publications/52888
Official URL:http://dx.doi.org/10.1080/10610270412331328826
Export this item as:BibTeX
EndNote
HTML Citation
Reference Manager

 

Repository Staff Only: item control page

Metis ID: 224849