Binding control and stoichiometry of ferrocenyl dendrimers at a molecular printboard

Share/Save/Bookmark

Nijhuis, Christian A. and Huskens, Jurriaan and Reinhoudt, David N. (2004) Binding control and stoichiometry of ferrocenyl dendrimers at a molecular printboard. Journal of the American Chemical Society, 126 (39). pp. 12266-12267. ISSN 0002-7863

[img] PDF
Restricted to UT campus only
: Request a copy
142kB
Abstract:Ferrocenyl-functionalized PPI dendrimers of generations 1-5 were adsorbed at self-assembled monolayers of heptathioether-functionalized B-cyclodextrin (B-CD) on gold. The dendrimers form stable supramolecular assemblies at the B-CD host surface having multivalent supramolecular interactions and could be electrochemically desorbed from the surface. Using cyclic voltammetry, the stoichiometries of the dendrimers at the surface could be determined for all generations, which were quantitatively confirmed for generations 1 and 2 by surface plasmon resonance titrations.
Item Type:Article
Copyright:© 2004 American Chemical Society
Faculty:
Science and Technology (TNW)
Research Group:
Link to this item:http://purl.utwente.nl/publications/49588
Official URL:http://dx.doi.org/10.1021/ja048271n
Export this item as:BibTeX
EndNote
HTML Citation
Reference Manager

 

Repository Staff Only: item control page

Metis ID: 222210