Molecular design approach to a stable heterometallic zirconium-titanium alkoxide - potential precursor of mixed-oxide ceramics

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Spijksma, Gerald I. and Bouwmeester, Henny J.M. and Blank, Dave H.A. and Kessler, Vadim G. (2004) Molecular design approach to a stable heterometallic zirconium-titanium alkoxide - potential precursor of mixed-oxide ceramics. Inorganic Chemistry Communications, 7 (8). pp. 953-955. ISSN 1387-7003

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Abstract:New heterometallic interesting trinuclear, Zr{η3, μ2-NH(C2H4O)2}3[Ti(OiPr)3]2 encountering a nona-coordinated central zirconium atom crystallizes at −30 °C from a solution of zirconium and titanium isopropoxides and diethanolamine (Zr:Ti:L=1:2:3) in hydrocarbons. Due to its solution stability, this structurally characterized compound is an attractive potential precursor in sol–gel technique for the preparation of mixed metal oxide materials.
Item Type:Article
Copyright:© 2004 Elsevier
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Science and Technology (TNW)
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Link to this item:http://purl.utwente.nl/publications/49506
Official URL:http://dx.doi.org/10.1016/j.inoche.2004.06.006
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Metis ID: 222016