Sampling small volumes of ambient ammonia using a miniaturized gas sampler


Timmer, Björn and Olthuis, Wouter and Berg, Albert van den (2004) Sampling small volumes of ambient ammonia using a miniaturized gas sampler. Lab on a Chip, 4 (3). pp. 252-255. ISSN 1473-0197

[img] PDF
Restricted to UT campus only
: Request a copy
Abstract:The development of a gas sampler for a miniaturized ambient ammonia detector is described. A micromachined channel system is realized in glass and silicon using powder blasting and anodic bonding. The analyte gas is directly mixed with purified water, dissolving the ammonia that will dissociate into ammonium ions. Carrier gas bubbles are subsequently removed from the liquid stream through a venting hole sealed with a microporous water repellent PTFE membrane. A flow restrictor is placed at the outlet of the sampler to create a small overpressure underneath the membrane, enabling the gas to leave through the membrane. Experiments with a gas flow of 1 ml min–1, containing ammonia concentrations ranging from 9.4 ppm to 0.6 ppm in a nitrogen carrier flow have been carried out, at a water flow of 20 µl min–1. The ammonium concentration in the sample solution is measured with an electrolyte conductivity detector. The measured values correspond with the concentration calculated from the initial ammonia concentration in the analyte gas, the fifty times concentration enhancement due to the gas–liquid volume difference and the theoretical dissociation equilibrium as a function of the resulting pH.
Item Type:Article
Copyright:© 2004 RSC Publishing
Electrical Engineering, Mathematics and Computer Science (EEMCS)
Research Group:
Link to this item:
Official URL:
Export this item as:BibTeX
HTML Citation
Reference Manager


Repository Staff Only: item control page

Metis ID: 218845