Cyclic hydrogen bond arrays: vibrational spectroscopic study of aminomethyl-substituted resorcinarene-based cavitands and their clathrates with THF

Dormann, Jörg and Ruoff, Andreas and Schatz, Jürgen and Middel, Oskar and Verboom, Willem and Reinhoudt, David N. (2003) Cyclic hydrogen bond arrays: vibrational spectroscopic study of aminomethyl-substituted resorcinarene-based cavitands and their clathrates with THF. Journal of Physical Organic Chemistry, 16 (1). pp. 21-26. ISSN 0894-3230

PDF
Restricted to UT campus only: Request a copy
95Kb

Abstract:	Mono- and tetrakis(aminomethyl)-substituted resorcinarene-based cavitands 1 and 2 and their clathrates 1 2·THF and 2·(THF)2 were investigated by FTIR spectroscopy and thermogravimetric analysis. Both hosts form stable clathrates with THF both in solution and in the solid state. Major intra- and intermolecular interactions could be identified and located by the use of vibrational spectroscopy. In all cases, dynamic cyclic intramolecular hydrogen bonds between the amino groups and neighbouring ether bridges are observable.
Item Type:	Article
Copyright:	© 2003 Wiley InterScience
Faculty:	Science and Technology (TNW)
Research Group:	Molecular Nanofabrication (MNF)
Link to this item:	http://purl.utwente.nl/publications/40835
Official URL:	http://dx.doi.org/10.1002/poc.562
Export this item as:	BibTeX EndNote HTML Citation Reference Manager

Show download statistics for this publication

Repository Staff Only: item control page

Metis ID: 215153