A vibrational spectroscopic study of clathrates of resorcarene-based cavitands

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Dormann, Jörg and Ruoff, Andreas and Schatz, Jürgen and Middel, Oskar and Verboom, Willem and Reinhoudt, David N. (2001) A vibrational spectroscopic study of clathrates of resorcarene-based cavitands. Journal of Physical Organic Chemistry, 14 (10). pp. 704-708. ISSN 0894-3230

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Abstract:By comparison of the fully assigned vibrational spectra obtained for resorcarene-based cavitands 2a and 2b, their clathrates with toluene and ethanol respectively, and free guest molecules, good structural models for the clathrates could be obtained merely based on Fourier transform infrared data. Using this novel technique, various different interactions between the host and guest in the solid state as well as the orientation of the included guest could be identified. In the case of cavitand 2a, the model obtained by this methodology could be validated by comparison with an experimental crystal structure analysis.
Item Type:Article
Additional information:663
Copyright:© 2001 Wiley InterScience
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Science and Technology (TNW)
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Link to this item:http://purl.utwente.nl/publications/36757
Official URL:http://dx.doi.org/10.1002/poc.440
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