9-(Guanidinomethyl)-10-vinylanthracene: a suitable fluorescent monomer for MIPs

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Zhang, Huiqi and Verboom, Willem and Reinhoudt, David N. (2001) 9-(Guanidinomethyl)-10-vinylanthracene: a suitable fluorescent monomer for MIPs. Tetrahedron Letters, 42 (26). pp. 4413-4416. ISSN 0040-4039

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Abstract:9-(Guanidinomethyl)anthracene derivatives with a bromo (6) or a vinyl group (10) at the 10-position have been prepared starting from 9-bromoanthracene (1). They show 1:1 complexation with carboxylic acids or carboxylates with K-values of 1.2–1.4×105 M−1 in deuteriomethanol. Copolymerization of 9-vinylanthracene, 9-(guanidinomethyl)-10-vinylanthracene hydrochloride (10), and the 1:1 complex of 10 and ammonium benzoate with ethyleneglycol dimethacrylate (EDMA) gave the polymers in 77–92% yield.
Item Type:Article
Copyright:© 2001 Elsevier Science
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Science and Technology (TNW)
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Link to this item:http://purl.utwente.nl/publications/36701
Official URL:http://dx.doi.org/10.1016/S0040-4039(01)00738-9
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