Importance of the surface exchange kinetics as rate limiting step in oxygen permeation through mixed-conducting oxides

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Bouwmeester, H.J.M. and Kruidhof, H. and Burggraaf, A.J. (1994) Importance of the surface exchange kinetics as rate limiting step in oxygen permeation through mixed-conducting oxides. Solid State Ionics, 72 (2). pp. 185-194. ISSN 0167-2738

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Abstract:Attention is drawn to the possible involvement of the surface exchange kinetics in limiting the rate of oxygen permeation through mixed-conducting oxide ceramics. A theoretical approach is provided with which it is possible to distinguish between surface exchange- and bulk diffusion controlled kinetics of oxygen permeation. New results on the oxygen permeability of perovskites La0.8Sr0.2CoO3−σ and SrCo0.8Fe0.2O3−σ are presented. The importance of the exchange reaction re to diffusion in limiting overall oxygen transport through (La,Sr)(Co,Fe)O3−σ perovskite-type oxides is emphasized.
Item Type:Article
Copyright:© 1994 Elsevier Science
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Science and Technology (TNW)
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Link to this item:http://purl.utwente.nl/publications/12672
Official URL:http://dx.doi.org/10.1016/0167-2738(94)90145-7
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Metis ID: 106853