Highly ordered films of neat calix[4]arenes for second order nonlinear optics

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Kelderman, Erik and Heesink, Gerard J.T. and Derhaeg, Lode and Verbiest, Thierry and Klaase, Piet T.A. and Verboom, Willem and Engbersen, Johan F.J. and Hulst van, Niek F. and Clays, Koen and Persoons, Andre and Reinhoudt, David N. (1993) Highly ordered films of neat calix[4]arenes for second order nonlinear optics. Advanced Materials, 5 (12). pp. 925-930. ISSN 0935-9648

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Abstract:In substituted calix[4]-arenes-cyclophanes consisting of four phenol moieties connected by methylene bridges-the number and also the relative positions of the donor and/or acceptor pi- conjugated (D-pi-A) units can be varied by changing the configuration. The Figure illustrates the cone configuration. The molecular and thin-film NLO properties of three tetra-D-pi- A-substituted calix[4]arenes, including their orientation in thin films and the stability of their NLO properties, are described.
Item Type:Article
Copyright:© 1993 Wiley-VCH
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Science and Technology (TNW)
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Link to this item:http://purl.utwente.nl/publications/12561
Official URL:http://dx.doi.org/10.1002/adma.19930051211
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Metis ID: 106742