Nitrocalix[4]arenes as molecules for second-order nonlinear optics


Kelderman, Erik and Derhaeg, Lode and Heesink, Gerard J.T. and Verboom, Willem and Engbersen, Johan F.J. and Hulst, Niek F. van and Persoons, Andre and Reinhoudt, David N. (1992) Nitrocalix[4]arenes as molecules for second-order nonlinear optics. Angewandte Chemie, International Edition in English, 31 (8). pp. 1075-1077. ISSN 0570-0833

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Abstract:The frequency-doubling of 820 nm laser light is o­ne of the properties of a series of nitrocalix-[4]arenes making them suitable, in principle, for the construction of a blue laser. Derivative 1 is the most promising, since it displays the greatest hyperpolarizability and the largest dipole moment and is stable as a film in a polymer matrix for long periods.
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Copyright:© 1991 Wiley Interscience
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Metis ID: 106730