Covalent capture of dynamic hydrogen-bonded assemblies

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Cardullo, F. and Crego Calama, M. and Snellink-Ruel, B.H.M. and Weidmann, J.-L. and Bielejewska, A. and Fokkens, R. and Nibbering, N.M.M. and Timmerman, P. and Reinhoudt, D.N. (2000) Covalent capture of dynamic hydrogen-bonded assemblies. Chemical Communications, 2000 (15). pp. 367-368. ISSN 1359-7345

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Abstract:Covalent linkage of the three calix[4]arene units in hydrogen-bonded assemblies 13(DEB)6via a threefold ring closing metathesis (RCM) reaction quantitatively converts the dynamic assemblies into covalent systems (123-membered macrocycles) that can be easily characterized using MALDI-TOF MS and HPLC.
Item Type:Article
Copyright:© Royal Society of Chemistry 2000
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Link to this item:http://purl.utwente.nl/publications/11639
Official URL:http://dx.doi.org/10.1039/a909459h
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Metis ID: 106263