Surface-confined metallodendrimers: isolated nanosize molecules


Huisman, Bart-Hendrik and Schönherr, Holger and Huck, Wilhelm T.S. and Friggeri, Arianna and Manen, Henk-Jan van and Menozzi, Edoardo and Vancso, G. Julius and Veggel, Frank C.J.M. van and Reinhoudt, David N. (1999) Surface-confined metallodendrimers: isolated nanosize molecules. Angewandte Chemie, International Edition in English, 38 (15). pp. 2248-2251. ISSN 0570-0833

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Abstract:The incorporation of dialkyl sulfide side chains in metallodendrimers is a simple method for their insertion into a monolayer of decanethiol formed by self-assembly on a gold surface. The dendrimer binds through the sulfide group to a defect in the monolayer on the gold surface (see picture). The surface concentration of the isolated dendrimer adsorbate can be regulated by the adsorption time (for example, 55 adsorbates on a surface of 200×200 nm2 after 20 h).
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Copyright:© 2008 WILEY-VCH Verlag
Science and Technology (TNW)
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