A modular approach to potential synthetic receptors with large surfaces based on crown[n]cavitands

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Higler, Irene and Boerrigter, Harold and Verboom, Willem and Kooijman, Huub and Spek, Anthony L. and Reinhoudt, David N. (1998) A modular approach to potential synthetic receptors with large surfaces based on crown[n]cavitands. European Journal of Organic Chemistry, 1998 (8). pp. 1597-1607. ISSN 1434-193X

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Abstract:Crown[n]cavitands were synthesized by alkylation of tetrahydroxycavitands with polyethyleneglycol ditosylates. The bridging of two hydroxy groups at adjacent aromatic rings by a pentaethyleneglycol unit is favored over the bridging of two hydroxy groups at opposite aromatic rings. The presence of a sodium base enhances the formation of the 1,2-crown[n]cavitand and improves the yield. The combination of 1,2-crown[6]cavitands with calix[4]arenes or resorcin[4]arenes resulted in potential receptor molecules with large hydrophobic surfaces.
Item Type:Article
Copyright:© 1998 WILEY-VCH Verlag
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Science and Technology (TNW)
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Link to this item:http://purl.utwente.nl/publications/11081
Official URL:http://dx.doi.org/10.1002/(SICI)1099-0690(199808)1998:8<1597::AID-EJOC1597>3.0.CO;2-1
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