A significant effect of anion binding ureas on the product ratio in het palladium(ii)-catalyzed hydrocarbonylation of alkenes

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Scheele, Jan and Timmerman, Peter and Reinhoudt, David N. (1998) A significant effect of anion binding ureas on the product ratio in het palladium(ii)-catalyzed hydrocarbonylation of alkenes. Chemical Communications, 1998 (23). pp. 2613-2614. ISSN 1359-7345

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Abstract:Hydrogen bonding of urea derivatives to the anionic ligands X of (dppp)PdX2 catalysts significantly increases the hydroacylation of cyclopentene relative to the hydroformylation, most probably due to a decreased coordination strength of the anionic ligands.
Item Type:Article
Copyright:© 1998 Royal Society of Chemistry
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Link to this item:http://purl.utwente.nl/publications/11058
Official URL:http://dx.doi.org/10.1039/a806722h
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Metis ID: 105973