Noncovalent assembly of a fifteen-component hydrogen-bonded nanostructure


Jolliffe, Katrina A. and Timmerman, Peter and Reinhoudt, David N. (1999) Noncovalent assembly of a fifteen-component hydrogen-bonded nanostructure. Angewandte Chemie, International Edition in English, 38 (7). pp. 933-937. ISSN 0570-0833

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Abstract:A total of 72 hydrogen bonds are formed in the spontaneous association of calix[4]arene tetramelamine and barbituric acid derivatives to give nanosized assemblies of the type represented in the picture. These consist of 15 components that assemble in a completely diastereoselective sense: of the eight possible diastereomers only the all-staggered diastereoisomer is obtained.
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Copyright:© 1999 Wiley InterScience
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Metis ID: 105960