Polysilylenes with ethynylphenyl-substituents

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Frey, H. and Schulenburg, E.-J. and Möller, M. and Noorlander-Bunt, H.G. and Engbersen, J.F.J. and Reinhoudt, D.N. (1995) Polysilylenes with ethynylphenyl-substituents. Acta Polymerica, 46 (1). pp. 45-49. ISSN 0323-7648

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Abstract:Ethynylphenyl-methyldichlorosilane (EPDMS) has been prepared as a new monomer for the synthesis of polysilylenes with triple bonds attached to the catenated Si chain. A series of copolymers with methylphenyldichlorosilane (MPDS) as well as the homopolymer, PEPMS, have been synthesized. The content of ethynylphenyl substituents was quantitatively analyzed by FTIR spectroscopy. The optical properties of the new polymers were studied with respect to potential - interaction. No significant bathochromic shift of the UV-absorption maximum could be detected. Unexpectedly, increasing content of incorporated EPMS units led to a decrease of the (-*) absorption. The ethynylphenyl-substituted polysilylenes exhibited strong, temperature-dependent fluorescence in solution as well as in films.
Item Type:Article
Copyright:© 1995 WILEY-VCH Verlag
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Science and Technology (TNW)
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Link to this item:http://purl.utwente.nl/publications/10548
Official URL:http://dx.doi.org/10.1002/actp.1995.010460105
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Metis ID: 105718